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This study the impact of different catalytic systems on the formation of structural defects among the macromolecular chain, in the molecular characteristics (average molecular weights per number (Mn), per weight (Mw), and polydispersity index (?)), along with the composition ratio of the two monomeric units within the main chain for a specific class of conjugated polymers through the utilization of size exclusion chromatography and proton nuclear magnetic resonance (1H-NMR) spectroscopy, respectively is examined. From the obtained results, the formation of the structural defects in the studied ?donor?acceptor? polymers is visualized and quantified by 1H-NMR. The alternating polymers containing the lower percentage of chemical defects demonstrate increased Mn and Mw values and increased absorption co-efficiency as recorded by UV?vis absorption spectroscopy. Therefore, it is evident that this work highlights optimum Stille cross-coupling polymerization conditions, which can be a guide rule for the synthesis of defect-free conjugated polymers.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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Novel phosphorescent heteroleptic iridium complexes with phenylpyridine and dibenzo-containing ligands are provided. Alkyl substitution at specific positions on the ligands gives rise to compounds with improved OLED properties, including saturated green emission.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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The advanced oxidation process (AOP) for the pretreatment of model palladium catalysts has been studied. Most standard metal analysis techniques are for metal ions free of organic ligands. Spent palladium catalysts contain organic ligands that need to be removed prior to analysis. AOP uses a combination of hydrogen peroxide and UV light to generate radicals that decompose such ligands, freeing up metals for further analysis. Palladium acetate Pd(OAc)2, palladium acetylacetonate Pd(acac)2, and tris(dibenzylideneacetone)dipalladium (Pd2(dba)3) were chosen as model precious metal catalysts for investigation. AOP was found to decompose ligands in Pd(OAc)2, Pd(acac)2 and give accurate Pd(II) quantification, while ligand decomposition and oxidation of Pd(0) to Pd(II) were demonstrated in treatments involving Pd2(dba)3. The effects of solubility of the palladium complexes, continuous addition of H2O2 during AOP treatments, sample pH, concentration of H2O2, and length of UV irradiation are reported.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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The glass transition temperature (Tg) is a key property that dictates the applicability of conjugated polymers. The Tg demarks the transition into a brittle glassy state, making its accurate prediction for conjugated polymers crucial for the design of soft, stretchable, or flexible electronics. Here we show that a single adjustable parameter can be used to build a relationship between the Tg and the molecular structure of 32 semiflexible (mostly conjugated) polymers that differ drastically in aromatic backbone and alkyl side chain chemistry. An effective mobility value, zeta, is calculated using an assigned atomic mobility value within each repeat unit. The only adjustable parameter in the calculation of zeta is the ratio of mobility between conjugated and non-conjugated atoms. We show that zeta correlates strongly to the Tg, and that this simple method predicts the Tg with a root-mean-square error of 13 C for conjugated polymers with alkyl side chains.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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The present invention provides compositions and methods for dedifferentiating lineage committed mammalian cells.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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The present invention relates to novel substituted (alpha,beta-fused butyrolactones, to processes for their preparation and to their use for the prevention and/or treatment of disorders caused by hyper- or hypofunction of the glutamatergic system, in particular of cerebral ischaemias, craniocerebral trauma, states of pain or CNS-mediated spasms.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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Perylene has had a tremendous impact in the history of material research for the molecular semiconductors. Among numerous derivatives of this polyaromatic hydrocarbon, perylene diimide (PDI) represents a promising class of organic materials envisioned as non-fullerene acceptors (NFAs) for the practical organic photovoltaic (OPV) applications due to their enhanced photo- and thermal stability and remarkably high electron affinity, some of which realize band-like transport properties. The present review guides some of the representative achievements in the development of rationally designed PDI systems, highlighting synthetic methodologies based on bay-functionalization strategies for creating well-designed molecular nanostructures and structure-performance relationship of perylene-based small molecular acceptors (SMAs) for the photovoltaic outcomes.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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Provided herein is a compound represented by the Formula (I) wherein said compounds are useful for the treatment of migraine. Also provided are processes for the preparation of compounds of Formula (I) and intermediates.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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The total syntheses of anithiactins A-C (1?3) and thiasporine A (4) have been achieved in good overall yields. The key reaction in the synthetic sequence was the Suzuki-Miyaura cross-coupling between 2-aminophenylboronic acid hydrochloride and methyl 2-bromothiazole-4-carboxylate forming the common intermediate methyl 2-(2-aminophenyl)thiazole-4-carboxylate (8), which could be further transformed by hydrolysis, alkylation, and aminolysis to give the four title natural products. This work represents the first total synthesis of anithiactin B (2) and C (3).

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method

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The present invention provides a method for the N-demethylation and/or N-acylation of an N-methylated heterocycle such as morphine alkaloids or tropane alkaloids. The method comprises reacting the heterocycle with an acylating agent in the presence of a metal catalyst.

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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method