Some scientific research about 14220-64-5

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Product Details of 14220-64-5, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd

Structures and fluorescent properties of picolinato zinc(II) and cadmium(II) complexes based on tridentate and tetradentate benzimidazole ligands

Five picolinato zinc(II) and cadmium(II) complexes, [Zn(ntb)(pic)]ClO4¡¤CH3OH¡¤2H2O (1), [Zn(bbma)(pic)]NO3¡¤2CH3OH (2), [Cd(ntb)(pic)]ClO4¡¤0.75CH3OH¡¤H2O (3), [Cd2(bbma)2(pic)2](ClO4)2 (4), and [Cd2(bbp)(bbp-H)(pic)2(C2H5OH)]ClO4 (5), have been synthesized, where pic is the anion of picolinic acid, ntb is tris(2-benzimidazolylmethyl)amine, bbma is bis(benzimidazol-2-yl-methyl)amine, and bbp is 2,6-bis(benzimidazol-2-yl)pyridine. All the complexes were characterized by X-ray single-crystal diffraction, elemental analysis, IR, fluorescence spectroscopy, and thermal gravimetric analysis. 1?3 are mononuclear complexes in which picolinate adopts a N,O-chelating mode. 4 is a symmetrical dinuclear complex bridged by two anti-parallel picolinates in a N,O,O-coordination mode. 5 is also a dinuclear complex in which only one picolinate is a bridge. A 1-D double chain is formed by extensive H-bonds and pi?pi stacking in 1, while single zigzag chains are formed in 5. Complexes 2?4 all exhibit 63-hcb 2-D frameworks. They extend to form four-connected 66-dia 3-D topological nets for 2 and 4 and five-connected 46¡¤64-bnn 3-D topological nets for 3. The five complexes show emission maxima in the blue region in the solid state.

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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method