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14871-92-2, Name is (2,2¡ä-Bipyridine)dichloropalladium(II), belongs to catalyst-palladium compound, is a common compound. Recommanded Product: (2,2¡ä-Bipyridine)dichloropalladium(II)In an article, once mentioned the new application about 14871-92-2.
Chemistry of Acetoacetanilide and Derivatives with Zero- and Di-valent Platinum and Palladium complexes; Crystal Structure of the Four-membered Ring Palladalactam Complex (bipy = 2,2′-bipyridyl)
Reaction of the complexes cis- with acetoacetanilide, o- or p-acetoacetanisidide mediated by silver(I) oxide gave, under mild conditions, high yields of the metallalactam complexes (R = Ph, C6H4OMe-o or p).The complexes have been fully characterised by multinuclear NMR spectroscopy, fast atom bombardment mass spectrometry, and by a single-crystal X-ray diffraction study carried out on the 2,2′-bipyridyl palladium derivative .The complex contains a slightly puckered palladalactam ring system (fold angle 17.5 deg).Reaction of acetoacetanilide with the zerovalent platinum complex in air gives exclusively the peroxometallacyclic complex , while reaction with gave a mixture of the peroxometallacycle plus the platinalactam complex .
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method