32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. category: catalyst-palladiumIn an article, once mentioned the new application about 32005-36-0.
In the palladium-catalyzed cyclization of allenic allylic esters using Pd(dba)2 as catalyst, it was shown that the allene acts as a carbon nucleophile. Intermediates were isolated and stereochemical studies established that the double bond of the allene has attacked the (pi-allyl)palladium intermediate on the face opposite to that of palladium. Copyright
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Reference:
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method