Synthetic Route of 14220-64-5, Because a catalyst decreases the height of the energy barrier, its presence increases the reaction rates of both the forward and the reverse reactions by the same amount.14220-64-5, Name is Bis(benzonitrile)palladium chloride, molecular formula is C14H10Cl2N2Pd. In a article£¬once mentioned of 14220-64-5
Self-assembly of dinuclear helical and nonhelical complexes with copper(I)
The ligand 1,3-bis(1-methylbenzimidazol-2-yl)benzene (mbzimbe, L3) reacts with copper(I) to give [Cu2(L3)2](ClO4)2. The crystal structure of this compound (Cu2C44H36N8Cl2O 8, a = 13.661 (1) A, b = 19.829 (3) A, c = 15.413 (2) A, orthorhombic, Pbca, Z = 4) shows a dinuclear centrosymmetrical nonhelical structure in which each copper is linearly coordinated by a benzimidazole group of each ligand. The complex displays a weak intramolecular stacking interaction between the benzene groups. This complex can be considered as a stereoconformer of the double-helical complex [Cu2(L1)2](ClO4)2 (L1; 2,6-bis(1-methylbenzimidazol-2-yl)pyridine). Conductivity measurements and UV-visible spectra show that the dimeric structures are maintained in solution in polar aprotic solvents. 1H NMR measurements show that [Cu2(L1)2]2+ retains its helical structure in solution. Comparison of helical and nonhelical structures with those formed by Cu(I) with related ligands allows discussion of the factors favoring the formation of self-assembled dinuclear complexes.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 14220-64-5
Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method