In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Safety of Bis(dibenzylideneacetone)palladium, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 32005-36-0, name is Bis(dibenzylideneacetone)palladium. In an article£¬Which mentioned a new discovery about 32005-36-0
Bimolecular fusion of [Pd3(mu-CN-C6H3Me2-2,6)3(CN-C6H3Me2-2,6)3] induced by Ph2GeH2: Formation of the redox-active Pd6Ge2 complex
The reaction of Ph2GeH2 with a planar tripalladium(0) complex, [Pd3(mu-CN-C6H3Me2-2,6)3(CN-C6H3Me2-2,6)3], selectively afforded a hexagonal bipyramidal Pd6Ge2 complex, [Pd6(mu-GePh2)2(CN-C6H3Me2-2,6)8(mu-CN-C6H3Me2-2,6)2]. The molecule is stabilized by bridging coordination of isonitrile and GePh2 ligands, although all the Pd-Pd bonds are weak, as revealed by DFT calculations. The resulting complex undergoes two successive redox processes at E1/2 =-1.35 and-1.03 V (vs. Fc+/Fc), which correspond to the stepwise oxidation of the Pd(0)6 complex.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method