32005-36-0, Name is Bis(dibenzylideneacetone)palladium, belongs to catalyst-palladium compound, is a common compound. Computed Properties of C34H28O2PdIn an article, once mentioned the new application about 32005-36-0.
Synthesis and X-ray structure of cationic beta-diimine palladium complexes containing pi-methallyl ligand
High yield of cationic palladium beta-diimine complexes [(CH 2(MeCNAr)2)Pd(eta3-C4H 7)][Y] (Ar = C6H5, Y = PF6 (8); 2-Me-C6H4, Y = PF6 (9); 2,6-Me 2-C6H3, Y = PF6 (10); 2,6-iPr 2-C6H3, Y = PF6 (11), Y = B(3,5-(CF3)2-C6H3)4 (12)) have been obtained by an oxidative addition of the methallyloxyphosphonium salts (5, 6) to a preformed complex Pd(dba)2 (7) in the presence of the beta-iminoamine ligands (1-4). These complexes are thermally stable and have been characterized by 1H and 13C{1H} NMR as well as IR spectroscopy. The structure of the cationic allyl palladium complex (12) has been solved by X-ray crystallography.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method