In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Quality Control of Bis(dibenzylideneacetone)palladium, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 32005-36-0, name is Bis(dibenzylideneacetone)palladium. In an article£¬Which mentioned a new discovery about 32005-36-0
Design and synthesis of alpha-carboxy nucleoside phosphonate analogues and evaluation as HIV-1 reverse transcriptase-targeting agents
The synthesis of the first series of a new class of nucleoside phosphonate analogues is described. Addition of a carboxyl group at the alpha position of carbocyclic nucleoside phosphonate analogues leads to a novel class of potent HIV reverse transcriptase (RT) inhibitors, alpha-carboxy nucleoside phosphonates (alpha-CNPs). Key steps in the synthesis of the compounds are Rh-catalyzed O-H insertion and Pd-catalyzed allylation reactions. In cell-free assays, the final products are markedly inhibitory against HIV RT and do not require phosphorylation to exhibit anti-RT activity, which indicates that the alpha-carboxyphosphonate function is efficiently recognized by HIV RT as a triphosphate entity, an unprecedented property of nucleoside monophosph(on)ates.
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Reference£º
Chapter 1 An introduction to palladium catalysis,
Palladium/carbon catalyst regeneration and mechanical application method